Synthesis of fluoro(aryloxo)alkaline earth metal cages by C–F bond activation

Deacon, Glen B., Junk, Peter C., and Moxey, Graeme J. (2010) Synthesis of fluoro(aryloxo)alkaline earth metal cages by C–F bond activation. Dalton Transactions, 39 (24). pp. 5620-5622.

[img] PDF (Published Version) - Published Version
Restricted to Repository staff only

[img] PDF (Supporting Online Material) - Supplemental Material
Restricted to Repository staff only

View at Publisher Website: http://dx.doi.org/10.1039/c0dt00122h
 
5
2


Abstract

Treatment of Ca or Sr metal with Hg(C6F5)2 and 2,4,6-trimethylphenol (HOmes) in 1,2-dimethoxyethane (dme) at room temperature resulted in C–F bond activation, giving rise to the unique fluoro(aryloxo)alkaline earth cages [Ca5(µ4-F)(µ3-F)4(µ-Omes)4(Omes)(dme)4] 1 and [Sr10(µ4-F)4(µ3-F)4(µ-Omes)12(dme)4] 2, which can be viewed as arrested fluorite structures.

Item ID: 29673
Item Type: Article (Research - C1)
ISSN: 1477-9234
Keywords: aryl-calcium; coordination; complexes; reagents; ligands; halides
Funders: Australian Research Council (ARC)
Date Deposited: 02 Oct 2013 10:34
FoR Codes: 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030204 Main Group Metal Chemistry @ 100%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
Downloads: Total: 2
More Statistics

Actions (Repository Staff Only)

Item Control Page Item Control Page