Sulfonato-encapsulated bismuth(III)oxido-clusters from Bi2O3 in water under mild conditions

Andrews, Philip C., Busse, Madleen, Junk, Peter C., Forsyth, Craig M., and Peiris, Roshani (2012) Sulfonato-encapsulated bismuth(III)oxido-clusters from Bi2O3 in water under mild conditions. Chemical Communications, 48 (61). pp. 7583-7585.

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DOI: 10.1039/c2cc33495j

View at Publisher Website: http://dx.doi.org/10.1039/c2cc33495j

Abstract

Treatment of Bi2O3 with the acids; S-(+)-10-camphorsulfonic, 2,4,6-mesitylenesulfonic and sulfamic, under sonication at room temperature in water for 2-4 h, results in the formation and subsequent crystallisation of polynuclear bismuth oxido-clusters; [Bi18O12(OH)(12)(O3S-Cam)(18)(H2O)(2)], [Bi38O45(O3S-Mes)(24)(H2O)(14)] and [Bi6O4(OH)(4)(O3SNH2)(6)].


Item ID:	29649
Item Type:	Article (Research - C1)
ISSN:	1364-548X
Keywords:	oxo-clusters; target sites; subsalicylate; hydrolysis; chemistry
Date Deposited:	02 Oct 2013 10:34
FoR Codes:	03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030204 Main Group Metal Chemistry @ 100%
SEO Codes:	97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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