Synthesis and characterisation of rare earth complexes supported by para-substituted cinnamate ligands

Deacon, Glen B., Forsyth, Maria, Junk, Peter C., Leary, Stuart G., and Lee, Winnie W. (2009) Synthesis and characterisation of rare earth complexes supported by para-substituted cinnamate ligands. Zeitschrift für Anorganische und Allgemeine Chemie, 635 (6-7). pp. 833-839.

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Abstract

The preparations and characterisations of a range of lanthanoid 4-(R)-substituted (4-Rcinn, R = OH, OMe NO(2), Cl), known to have good anticorrosion properties, are reported. The crystal structure of [Ce(4-OHcinn)(3)(MeOH)(2)(H(2)O)]center dot MeOH is a polymer, in which the cerium atoms are nonacoordinate, and adjacent cerium atoms are bridged by either two bridging bidentate or two bridging tridentate carboxylate ligands. Each cerium atom also has one monodentate 4-hydroxycinnamate ligand, one aqua ligand, and two methanol ligands.

Item ID: 29637
Item Type: Article (Research - C1)
ISSN: 1521-3749
Keywords: lanthanides, cinnamates, x-ray diffraction, rare earth compounds
Funders: Australian Research Council (ARC) Special Centre for Green Chemistry
Date Deposited: 02 Oct 2013 10:34
FoR Codes: 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030202 f-Block Chemistry @ 100%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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