Synthesis and characterisation of rare earth complexes supported by para-substituted cinnamate ligands
Deacon, Glen B., Forsyth, Maria, Junk, Peter C., Leary, Stuart G., and Lee, Winnie W. (2009) Synthesis and characterisation of rare earth complexes supported by para-substituted cinnamate ligands. Zeitschrift für Anorganische und Allgemeine Chemie, 635 (6-7). pp. 833-839.
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Abstract
The preparations and characterisations of a range of lanthanoid 4-(R)-substituted (4-Rcinn, R = OH, OMe NO(2), Cl), known to have good anticorrosion properties, are reported. The crystal structure of [Ce(4-OHcinn)(3)(MeOH)(2)(H(2)O)]center dot MeOH is a polymer, in which the cerium atoms are nonacoordinate, and adjacent cerium atoms are bridged by either two bridging bidentate or two bridging tridentate carboxylate ligands. Each cerium atom also has one monodentate 4-hydroxycinnamate ligand, one aqua ligand, and two methanol ligands.
| Item ID: | 29637 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1521-3749 |
| Keywords: | lanthanides, cinnamates, x-ray diffraction, rare earth compounds |
| Funders: | Australian Research Council (ARC) Special Centre for Green Chemistry |
| Date Deposited: | 02 Oct 2013 10:34 |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030202 f-Block Chemistry @ 100% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
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