Zuyls, Agustino, Roesky, Peter W., Deacon, Glen B., Konstas, Kristina, and Junk, Peter C. (2008) Lanthanide formamidinates as improved catalysts for the Tishchenko reaction. European Journal of Inorganic Chemistry, 2008 (4). pp. 693-697.

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Abstract

The tris(formamidinato)lanthanum(III) complexes [La(o-TolForm)3(thf)2] [1; o-TolForm = N,N'-bis(o-tolyl)formamidinate], [La(XylForm)3(thf)] [2; XylForm = N,N'-bis(2,6-dimethylphenyl)formamidinate], and [La(EtForm)3] [3, EtForm = N,N'-bis(2,6-diethylphenyl)formamidinate] are a new class of precatalysts for the Tishchenko reaction. Their catalytic activity is a result of their high Lewis acidity and the ease with which the ligand spheres can be interchanged. For the dimerization of benzaldehyde to give benzyl benzoate, which is a benchmark reaction, compound 1 is, to the best of our knowledge, the most active catalyst ever reported. On a preparative scale, the reaction can be performed in the absence of solvent. A range of aromatic, heteroaromatic, and aliphatic aldehydes was rapidly converted into the corresponding esters by using catalysts 1–3.

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