Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster

Gee, William J., MacLellan, Jonathan G., Forsyth, Craig M., Moubaraki, Boujemaa, Murray, Keith S., Andrews, Philip C., and Junk, Peter C. (2012) Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster. Inorganic Chemistry, 51 (16). pp. 8661-8663.

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Abstract

Sequestration of peroxide derived from molecular oxygen has resulted in the templated synthesis of a terbium picolinate cluster, isolated as a 2D sodiated network in the solid state. This first example of an air-stable rare-earth peroxide cluster represents key evidence for a peroxide-containing intermediate in rare-earth-cluster-catalyzed oxidation reactions. Luminescent and magnetic properties have also been investigated.

Item ID: 25255
Item Type: Article (Research - C1)
ISSN: 1520-510X
Funders: Australian Research Council (ARC), Monash University
Date Deposited: 23 Apr 2013 05:51
FoR Codes: 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030202 f-Block Chemistry @ 100%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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