Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster
Gee, William J., MacLellan, Jonathan G., Forsyth, Craig M., Moubaraki, Boujemaa, Murray, Keith S., Andrews, Philip C., and Junk, Peter C. (2012) Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster. Inorganic Chemistry, 51 (16). pp. 8661-8663.
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Abstract
Sequestration of peroxide derived from molecular oxygen has resulted in the templated synthesis of a terbium picolinate cluster, isolated as a 2D sodiated network in the solid state. This first example of an air-stable rare-earth peroxide cluster represents key evidence for a peroxide-containing intermediate in rare-earth-cluster-catalyzed oxidation reactions. Luminescent and magnetic properties have also been investigated.
| Item ID: | 25255 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1520-510X |
| Funders: | Australian Research Council (ARC), Monash University |
| Date Deposited: | 23 Apr 2013 05:51 |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030202 f-Block Chemistry @ 100% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
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