Preparation of 7,8-diazaphencyclone and its use in the construction of rigid, space-separated 1,10-phenanthroline donor-acceptor systems: New ligands for metal complexation
Warrener, Ronald N., Houghton, Mark A., Schultz, Austin C., Keene, F. Richard, Kelso, Laurence S., Dash, Robert, and Butler, Douglas N. (1996) Preparation of 7,8-diazaphencyclone and its use in the construction of rigid, space-separated 1,10-phenanthroline donor-acceptor systems: New ligands for metal complexation. Chemical Communications, 1996. pp. 1151-1152.
PDF (Published Version)
- Published Version
Restricted to Repository staff only |
Abstract
7,8-Diazaphencyclone 7 is used as a delivery reagent to fuse 1,10-phenanthroline groups onto alkenic centres of rigid spacer molecular racks (molracs); molrac alkenes containing redox-active donor-acceptor chromophores yield molrac diads whose metal complexes, e.g. 26, are suitable for mechanistic studies involving intramolecular electron transfer.
Item ID: | 22835 |
---|---|
Item Type: | Article (Research - C1) |
ISSN: | 1364-548X |
Keywords: | ruthenium |
Date Deposited: | 08 Aug 2012 04:04 |
FoR Codes: | 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 30% 03 CHEMICAL SCIENCES > 0303 Macromolecular and Materials Chemistry > 030306 Synthesis of Materials @ 70% |
SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
Downloads: |
Total: 1 |
More Statistics |