Chiral [Ru(pp)₂(CO)₂]²⁺ species (pp = bidentate polypyridyl ligand) and their use in the stereoselective synthesis of ligand-bridge dinuclear complexes

Rutherford, Todd J., Quagliotto, Michael G., and Keene, F. Richard (1995) Chiral [Ru(pp)₂(CO)₂]²⁺ species (pp = bidentate polypyridyl ligand) and their use in the stereoselective synthesis of ligand-bridge dinuclear complexes. Inorganic Chemistry, 34 (15). pp. 3857-3858.

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Abstract

[Extract]The decarbonylation of chiral [Ru(pp)₂(CO)₂]²⁺ (pp = bidentate polypyridyl ligands) in the presence of excess pp shows stereoretention in the [Ru(pp)₃]²⁺ product, and under the same conditions, its reaction with chiral [Ru(pp')₂(BL)]²⁺ centers (pp and pp' may or may not be identical; BL = bridging ligand) allows synthesis of specific diastereoisomeric forms of the dinuclear species [(pp)₂Ru(BL)Ru(pp')₂]⁴⁺.

Item ID: 22813
Item Type: Article (Research - C1)
ISSN: 1520-510X
Keywords: sephadex; cation
Date Deposited: 16 Aug 2012 05:25
FoR Codes: 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 100%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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