Reduction of terminal alkynes mediated by tris(2,2'-bipyridine)cobalt(I)
Reitsma, David A., and Keene, F. Richard (1994) Reduction of terminal alkynes mediated by tris(2,2'-bipyridine)cobalt(I). Organometallics, 13 (4). pp. 1351-1354.
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DOI: 10.1021/om00016a043
View at Publisher Website: http://dx.doi.org/10.1021/om00016a043
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Abstract
In buffered aqueous ethanolic solution, phenylacetylene is reduced to styrene by [Co(bpy)₃]⁺ (bpy = 2,2'-bipyridine). In solutions of lower proton availability the predominant products were oligomeric, including coupled species such as 1,4-diphenylbutenyne.
| Item ID: | 22806 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1520-6041 |
| Keywords: | crystal-structure; complexes; hydrogenation; 1-alkynes; water; trans |
| Date Deposited: | 16 Aug 2012 04:24 |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 100% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
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