Resolution, X-ray structure and absolute configuration of a double-stranded helical diiron(II) bis(terpyridine) complex

Rapenne, Gwénaël, Patterson, Bradley T., Sauvage, Jean-Pierre, and Keene, F. Richard (1999) Resolution, X-ray structure and absolute configuration of a double-stranded helical diiron(II) bis(terpyridine) complex. Chemical Communications (18). pp. 1853-1854.

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Abstract

A dinuclear double helix constructed around two iron(II) bis(terpyridine) centres has been resolved by preparative column chromatography, several tens of milligrams of each enantiomer were obtained, with an excellent enantiomeric excess.

Item ID: 22804
Item Type: Article (Research - C1)
ISSN: 1364-548X
Keywords: trinuclear complexes; ligands; stereoisomers; dinuclear; 1,4,5,8,9,12-hexaazatriphenylene; stereochemistry; diruthenium(II) ruthenium(ii)
Date Deposited: 10 Aug 2012 05:00
FoR Codes: 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 100%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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