Resolution, X-ray structure and absolute configuration of a double-stranded helical diiron(II) bis(terpyridine) complex
Rapenne, Gwénaël, Patterson, Bradley T., Sauvage, Jean-Pierre, and Keene, F. Richard (1999) Resolution, X-ray structure and absolute configuration of a double-stranded helical diiron(II) bis(terpyridine) complex. Chemical Communications (18). pp. 1853-1854.
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DOI: 10.1039/a905135j
View at Publisher Website: http://dx.doi.org/10.1039/a905135j
Abstract
A dinuclear double helix constructed around two iron(II) bis(terpyridine) centres has been resolved by preparative column chromatography, several tens of milligrams of each enantiomer were obtained, with an excellent enantiomeric excess.
Item ID: | 22804 |
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Item Type: | Article (Research - C1) |
ISSN: | 1364-548X |
Keywords: | trinuclear complexes; ligands; stereoisomers; dinuclear; 1,4,5,8,9,12-hexaazatriphenylene; stereochemistry; diruthenium(II) ruthenium(ii) |
Date Deposited: | 10 Aug 2012 05:00 |
FoR Codes: | 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 100% |
SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
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