Keene, F. R., and Searle, G.H. (1972) Isomers of the bis(diethylenetriamine)cobalt(III) ion and a new source of optical activity. Inorganic Chemistry, 11 (1). pp. 148-156.

PDF (Published Version) - Published Version Restricted to Repository staff only

Abstract

The three geometric isomers of the [Co(dien)₂]⁸⁺ ion s-cis, u-cis, and trans have been separated by various methods, and the u-cis and trans isomers have been resolved into optical isomers through diastereoisomer formation. The configurations have been unequivocally assigned to these geometric forms from the different racemization behavior of the u-cis and trans optical isomers. Factors determining relative isomer stabilities are discussed, and infrared and pmr criteria for assigning isomer configurations are examined.

Item ID:	22789
Item Type:	Article (Research - C1)
ISSN:	1520-510X
Date Deposited:	04 Oct 2012 04:54
FoR Codes:	03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 100%
SEO Codes:	97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
Downloads:	Total: 3
	More Statistics