Microphotochemistry: 4,4'-Dimethoxybenzophenone mediated photodecarboxylation reactions involving phthalimides

Shvydkiv, Oksana, Nolan, Kieran, and Oelgemöller, Michael (2011) Microphotochemistry: 4,4'-Dimethoxybenzophenone mediated photodecarboxylation reactions involving phthalimides. Beilstein Journal of Organic Chemistry, 7. pp. 1055-1063.

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Abstract

A series of 4,4'-dimethoxybenzophenone mediated intra- and intermolecular photodecarboxylation reactions involving phthalimides have been examined under microflow conditions. Conversion rates, isolated yields and chemoselectivities were compared to analogous reactions in a batch photoreactor. In all cases investigated, the microreactions gave superior results thus proving the superiority of microphotochemistry over conventional technologies.

Item ID: 17760
Item Type: Article (Research - C1)
ISSN: 1860-5397
Keywords: microflow; microreactor; photochemistry; photodecarboxylation; phthalimide
Additional Information:

© 2011 Shvydkiv et al; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc)

Date Deposited: 11 Aug 2011 04:26
FoR Codes: 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 30%
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 20%
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030501 Free Radical Chemistry @ 50%
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