Back to the roofs – the solarchemical production of fine chemicals with sunlight
Oelgemöller, Michael, Jung, Christian, Ortner, Jürgen, Mattay, Jochen, Schiel, Christian, and Zimmermann, Elmar (2004) Back to the roofs – the solarchemical production of fine chemicals with sunlight. In: Proceedings of 2004 International Solar Energy Conference. 65021. pp. 523-531. From: ISEC 2004 International Solar Energy Conference, 11-14 July 2004, Portland, OR, USA.
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Abstract
Three photochemical reactions were performed successfully under solar irradiation conditions: the photoacylation of quinones with aldehydes and the rose bengal sensitized photooxygenations of citronellol or 1,5-dihydroxynaphthalene. All reactions were easily performed on multigram to kilogram scales using cheap and commercially available starting materials, and yielded important key-intermediates for industrial applications.
Item ID: | 17067 |
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Item Type: | Conference Item (Research - E1) |
ISBN: | 978-0-89553-176-6 |
Keywords: | solarchemistry, production of fine chemicals, solar reactors, "Photo-Friedel-Crafts acylation", quinones, photooxygenations, citronellol, juglone |
Additional Information: | Proceedings of the 2004 International Solar Energy Conference, Portland, OR, USA, 11-14 July 2004. ISBN: |
Date Deposited: | 25 Aug 2011 00:00 |
FoR Codes: | 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 40% 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030504 Organic Green Chemistry @ 40% 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 20% |
SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
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