Photosensitized addition of isopropanol to furanones in a continuous-flow dual capillary microreactor

Yavorskyy, Alexander, Shvydkiv, Oksana, Nolan, Kieran, Hoffmann, Norbert, and Oelgemöller, Michael (2011) Photosensitized addition of isopropanol to furanones in a continuous-flow dual capillary microreactor. Tetrahedron Letters , 52 (2). pp. 278-280.

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Abstract

A novel continuous-flow photoreactor with parallel capillaries was constructed and successfully tested for the DMBP-sensitized addition of isopropanol to furanones. Complete conversions were achieved after a maximum of 10 min of irradiation with a single 350 nm lamp. The results were compared to analogous batch experiments using a conventional Rayonet chamber reactor equipped with 16 UVA lamps. The capillary tower generally showed higher space-time yields.

Item ID: 16783
Item Type: Article (Research - C1)
ISSN: 1873-3581
Keywords: photoaddition; furanones; photochemistry; microreactor; microcapillary; continuous-flow synthesis
Date Deposited: 16 Jun 2011 00:46
FoR Codes: 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 40%
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 40%
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030504 Organic Green Chemistry @ 20%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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