Crystal and molecular structure of potassium trans-bis(iminodiacetato)cobaltate(III)-2H2O

Junk, Peter C., and Smith, Matthew K. (2002) Crystal and molecular structure of potassium trans-bis(iminodiacetato)cobaltate(III)-2H2O. Journal of Coordination Chemistry, 55 (9). pp. 1091-1096.

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The combination of iminodiacetic acid (H2ida) with cobalt(II) chloride hexahydrate in the presence of sodium hydroxide, followed by heating, produces the trans-facial isomer of K[Co(ida)2]·2H2O. This compound contains extensive intermolecular and intramolecular coordination and hydrogen bonding involving the potassium ions, and results in a complex three-dimensional structure in which each potassium ion is immediately surrounded by six cobalt centers.

Item ID: 13565
Item Type: Article (Research - C1)
ISSN: 1029-0389
Keywords: crystallography; inorganic chemistry
Date Deposited: 23 Dec 2010 01:11
FoR Codes: 03 CHEMICAL SCIENCES > 0306 Physical Chemistry (incl Structural) > 030606 Structural Chemistry and Spectroscopy @ 49%
03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 40%
03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030204 Main Group Metal Chemistry @ 10%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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