Formation of folded complexes retaining intramolecular H-bonding in the extraction of nickel(II) by phenolic oxime and aliphatic diamine ligands
Hultgren, Victoria M., Atkinson, Ian M., Beddoes, Roy L., Collinson, David, Garner, C. David, Helliwell, Maeleine, Lindoy, Leonard F., and Tasker, Peter A. (2001) Formation of folded complexes retaining intramolecular H-bonding in the extraction of nickel(II) by phenolic oxime and aliphatic diamine ligands. Chemical Communications, 6. pp. 573-574.
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DOI: 10.1039/b009267n
View at Publisher Website: http://dx.doi.org/10.1039/b009267n
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Abstract
Solvent extraction of Ni^II by phenolic oximes is enhanced significantly by addition of aliphatic diamines; octahedral [Ni(II)(phenolate-oxime)₂(diamine)] complexes have been characterised that contain a novel folded conformation, retaining intramolecular hydrogen bonding between the two oxime ligands.
| Item ID: | 13144 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1364-548X |
| Keywords: | hydrogen bonding; macrocycle; solvent extraction; X-ray crystallography |
| Date Deposited: | 28 Feb 2013 02:45 |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0301 Analytical Chemistry > 030108 Separation Science @ 66% 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 34% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
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