Kühl, Olaf, Junk, Peter C., and Hey-Hawkins, Evamarie (2000) Facile synthesis and molecular structure of [Ni(PPh2NHPh)4]. Zeitschrift für Anorganische und Allgemeine Chemie, 626 (7). pp. 1591-1594.

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Abstract

NiCl₂ · 6 H₂O readily reacts with PPh₂NHPh in the presence of zinc dust to yield the homoleptic nickel(0) tetrakis-phosphine complex [Ni(PPh₂NHPh)₄] (1). 1 crystallises triclinic P1 (no. 2), with a = 14.656(1), b = 17.124(2), c = 17.424(1) Å, α = 95.998(1), β = 111.845(1), γ= 111.402(1)°, V = 3630.04(5) Å3, Z = 2, R values [I > 2σ(I)]: R1 = 0.0554, all data: wR2 = 0.1720. The nickel atom is coordinated in a distorted tetrahedral fashion by four phosphorus atoms, resembling a compressed tetrahedron along one of the non-crystallographic S₄ axes.

Item ID:	13057
Item Type:	Article (Research - C1)
ISSN:	1521-1749
Date Deposited:	16 Jul 2012 04:05
FoR Codes:	03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 51% 03 CHEMICAL SCIENCES > 0306 Physical Chemistry (incl Structural) > 030606 Structural Chemistry and Spectroscopy @ 49%
SEO Codes:	97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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