Synthesis, structure and optical characteristics of pyridyl substituted diketonates of lanthanoids

Brück, Stefan, Hilder, Matthias, Junk, Peter C., and Kynast, Ulrich H. (2000) Synthesis, structure and optical characteristics of pyridyl substituted diketonates of lanthanoids. Inorganic Chemistry Communications, 3 (11). pp. 666-670.

[img] PDF (Published Version) - Published Version
Restricted to Repository staff only

View at Publisher Website: http://dx.doi.org/10.1016/S1387-7003(00)...
 
14
1


Abstract

Lanthanoid complexes of a dipyridylsubstituted β-diketonate ligand have been prepared and their structure and optical characteristics have been explored. The structure of these complexes are ten-coordinate centrosymmetric dimers with quadruply bridging diketonate ligands, terminal diketonate ligands and ‘dangling' and bound pyridyl nitrogen atoms. The europium complex diplays strongly luminescent properties while the terbium analogue is completely quenched.

Item ID: 12881
Item Type: Article (Research - C1)
ISSN: 1879-0259
Date Deposited: 17 Jul 2012 01:42
FoR Codes: 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030202 f-Block Chemistry @ 100%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
Downloads: Total: 1
More Statistics

Actions (Repository Staff Only)

Item Control Page Item Control Page