Photoacylations of 2-substituted 1,4-naphthoquinones: a concise access to biologically active quinonoid compounds
Waske, Prashant A., Mattay, Jochen, and Oelgemöller, Michael (2006) Photoacylations of 2-substituted 1,4-naphthoquinones: a concise access to biologically active quinonoid compounds. Tetrahedron Letters, 47 (8). pp. 1329-1332.
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Abstract
Photochemical acylations of 2-substituted-1,4-naphthoquinones with various aldehydes furnished acylated hydroquinones and acylated quinones in moderate to good combined yields. All reactions are easily performed and open a rapid access to biologically active compounds. For the 2-methyl-1,4-naphthoquinone/butyraldehyde pair, a novel tri-keto compound has been additionally isolated.
| Item ID: | 10220 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1873-3581 |
| Keywords: | photoacylation; quinones; aldehydes; addition reactions; photochemistry |
| Date Deposited: | 16 Apr 2010 01:47 |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 100% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
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