Photodecarboxylative cyclizations of ω-phthalimido-ortho-phenoxy carboxylates
Kim, Ae Rhan, Lee, Kyoung-Sub, Lee, Cheon-Woo, Yoo, Dong Jin, Hatoum, Fadi, and Oelgemöller, Michael (2005) Photodecarboxylative cyclizations of ω-phthalimido-ortho-phenoxy carboxylates. Tetrahedron Letters, 46 (19). pp. 3395-3398.
![[img]](https://researchonline.jcu.edu.au/style/images/fileicons/application_pdf.png) |
PDF (Published Version)
Restricted to Repository staff only |
View at Publisher Website: http://dx.doi.org/10.1016/j.tetlet.2005....
18
1
Abstract
ω-Phthalimido-ortho-phenoxy carboxylates efficiently undergo photodecarboxylative cyclizations in reasonable to good yields of 12–75%. Although the photocyclization efficiency decreases with increasing carbon chain lengths, target ring sizes up to 15 are successfully realized. Likewise, intermolecular photodecarboxylative additions of ω-phenoxy carboxylates to N-methyl phthalimide give hydroxyphthalimidines in yields of 45–73%.
| Item ID: | 10219 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 0040-4039 |
| Keywords: | Photodecarboxylation; Phthalimides; Cyclizations; Addition reactions; Photoinduced electron transfer |
| Date Deposited: | 13 Apr 2010 05:19 |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 100% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
| Downloads: |
Total: 1 |
| More Statistics |
Actions (Repository Staff Only)
 |
Item Control Page |