A deca-9-fluorenolato-deca-samarium oxide cage
Werner, Daniel, Deacon, Glen B., and Junk, Peter C. (2018) A deca-9-fluorenolato-deca-samarium oxide cage. European Journal of Inorganic Chemistry, 2018 (20-21). pp. 2241-2246.
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View at Publisher Website: https://doi.org/10.1002/ejic.201800330
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Abstract
The 9-fluorenone (fn) ketyl in [Yb-III(DippForm)(2)(fn-O)] {DippForm = N,N-bis(2,6-diisopropylphenyl)formamidinate}, underwent reduction to the dianion ({C13H8}-O) upon single electron transfer from (SmI2)-I-II(thf)(2). The dianion was obtained as a decanuclear, deca-9-fluorenolato, tetraoxido mixed-oxidation-state samarium cage [Sm10O4{(C13H8)-O}(10)(thf)(10)], obtained after ligand redistribution. The structure is relevant to the deoxygenation of ketones by lanthanoid metals.
| Item ID: | 55034 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1099-0682 |
| Keywords: | cage compounds, ketones, cyclopentadienyl ligands, oxido ligands, redox chemistry |
| Funders: | Australian Research Council (ARC) |
| Projects and Grants: | ARC DP160101640 |
| Date Deposited: | 15 Aug 2018 07:42 |
| FoR Codes: | 34 CHEMICAL SCIENCES > 3402 Inorganic chemistry > 340203 F-block chemistry @ 100% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
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