Photodecarboxylations in an advanced meso-scale continuous-flow photoreactor

Josland, Sam, Mumtaz, Saira, and Oelgemöller, Michael (2016) Photodecarboxylations in an advanced meso-scale continuous-flow photoreactor. Chemical Engineering and Technology, 39 (1). pp. 81-87.

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Abstract

Selected photodecarboxylations of phthalimides were realized under continuous flow conditions using an advanced meso-scale photoreactor. The improved efficiency, yields, and productivities of these photochemical reactions highlight the benefits of using flow as opposed to conventional batch operation modes. Flow chemistry furthermore allows for an easy combination of multiple reaction steps in series. This is demonstrated by the successful synthesis of a pharmaceutical target molecule through a tandem photochemical-thermal procedure carried out in uninterrupted flow.

Item ID: 42182
Item Type: Article (Research - C1)
ISSN: 1521-4125
Keywords: continuous-flow chemistry, multistep synthesis, photochemistry, photodecarboxylation
Funders: Australian Research Council (ARC), James Cook University (JCU)
Projects and Grants: ARC DP130100794, JCU RIBG 2014
Date Deposited: 14 Apr 2016 23:27
FoR Codes: 34 CHEMICAL SCIENCES > 3405 Organic chemistry > 340503 Organic chemical synthesis @ 60%
34 CHEMICAL SCIENCES > 3405 Organic chemistry > 340505 Physical organic chemistry @ 40%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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