Schiel, Christian, Oelgemoeller, Michael, and Mattay, Jochen (2001) Photoacylation of electron-rich quinones: an application of the "Photo-Friedel–Crafts Reaction". Synthesis, 2001 (8). pp. 1275-1279.

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Abstract

Irradiation of substituted 1,4-benzo- or 1,4-naphthoquinones in the presence of several aldehydes resulted in the formation of acylated hydroquinones in good yields. In the case of 5-acetyloxy naphthoquinone 8, both regioisomers were formed, but the 2,8-isomer was favored in all cases examined. Even acylated tetrahydroxy naphthalenes became available in good yields by this method.

Item ID:	29973
Item Type:	Article (Research - C1)
ISSN:	1437-210X
Keywords:	acylation, quinones, photochemistry
Funders:	Arbeitsgemeinschaft Solar, Themenfeld: Solare Chemie und Solare Materialforschung
Date Deposited:	16 Jul 2014 04:23
FoR Codes:	03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 20% 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030504 Organic Green Chemistry @ 80%
SEO Codes:	97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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