Synthesis of fluoro(aryloxo)alkaline earth metal cages by C–F bond activation

Deacon, Glen B., Junk, Peter C., and Moxey, Graeme J. (2010) Synthesis of fluoro(aryloxo)alkaline earth metal cages by C–F bond activation. Dalton Transactions, 39 (24). pp. 5620-5622.

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DOI: 10.1039/c0dt00122h

View at Publisher Website: http://dx.doi.org/10.1039/c0dt00122h

Abstract

Treatment of Ca or Sr metal with Hg(C6F5)2 and 2,4,6-trimethylphenol (HOmes) in 1,2-dimethoxyethane (dme) at room temperature resulted in C–F bond activation, giving rise to the unique fluoro(aryloxo)alkaline earth cages [Ca5(µ4-F)(µ3-F)4(µ-Omes)4(Omes)(dme)4] 1 and [Sr10(µ4-F)4(µ3-F)4(µ-Omes)12(dme)4] 2, which can be viewed as arrested fluorite structures.


Item ID:	29673
Item Type:	Article (Research - C1)
ISSN:	1477-9234
Keywords:	aryl-calcium; coordination; complexes; reagents; ligands; halides
Funders:	Australian Research Council (ARC)
Date Deposited:	02 Oct 2013 10:34
FoR Codes:	03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030204 Main Group Metal Chemistry @ 100%
SEO Codes:	97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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