Deacon, Glen B., Harika, Rita, Junk, Peter C., Skelton, Brian W., and White, Allan H. (2009) Correlated substituent rotation in the 1,2-benzenedisulfonate anion: the structure of the hydrated potassium salt. Journal of Coordination Chemistry, 62 (19). pp. 3098-3109.

PDF (Published Version) - Published Version Restricted to Repository staff only

 

1

1

Abstract

Structure determinations have previously been recorded on the dipotassium and potassium tetramethylammonium salts of 1,2-benzenedisulfonic acid (methanol solvate and hydrate, respectively), as a platform for examining the gear-like interactions of adjacent sulfonate substituents on the aromatic ring. The present report records a single crystal X-ray study of the hydrated potassium salt, showing it to be 8K2[(O3S)2C6H4] · 11H2O, with eight independent anions in the asymmetric unit, enabling a more broadly-based consideration of substituent dispositions.

Actions (Repository Staff Only)

Item Control Page