Preparation of 7,8-diazaphencyclone and its use in the construction of rigid, space-separated 1,10-phenanthroline donor-acceptor systems: New ligands for metal complexation

Warrener, Ronald N., Houghton, Mark A., Schultz, Austin C., Keene, F. Richard, Kelso, Laurence S., Dash, Robert, and Butler, Douglas N. (1996) Preparation of 7,8-diazaphencyclone and its use in the construction of rigid, space-separated 1,10-phenanthroline donor-acceptor systems: New ligands for metal complexation. Chemical Communications, 1996. pp. 1151-1152.

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Abstract

7,8-Diazaphencyclone 7 is used as a delivery reagent to fuse 1,10-phenanthroline groups onto alkenic centres of rigid spacer molecular racks (molracs); molrac alkenes containing redox-active donor-acceptor chromophores yield molrac diads whose metal complexes, e.g. 26, are suitable for mechanistic studies involving intramolecular electron transfer.

Item ID: 22835
Item Type: Article (Refereed Research - C1)
Keywords: ruthenium
ISSN: 1364-548X
Date Deposited: 08 Aug 2012 04:04
FoR Codes: 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 30%
03 CHEMICAL SCIENCES > 0303 Macromolecular and Materials Chemistry > 030306 Synthesis of Materials @ 70%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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