Diastereoisomeric forms of ligand-bridged dimetallic diruthenium(II) and ruthenium(II)–osmium(II) species containing bidentate polypyridyl ligands

Reitsma, David R., and Keene, F. Richard (1993) Diastereoisomeric forms of ligand-bridged dimetallic diruthenium(II) and ruthenium(II)–osmium(II) species containing bidentate polypyridyl ligands. Dalton Transactions (18). pp. 2859-2860.

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Abstract

A new general synthetic route is reported for dinuclear species of the type [((L(subscript t)₂)RuL(subscript b)Ru(L(subscript t)')₂]⁴⁺ or [(L(subscript t))₂RuL(subscript b)Os(L(subscript t)')₂]⁴⁺(L(subscript t)' L(subscript t)'= bidentate polypyridyl ligands, L(subscript t)≠ L(subscript t)'; L(subscript b)= bridging ligand), together with the chromatographic separation and characterization of the diastereoisomeric pairs of the dimers.

Item ID: 22805
Item Type: Article (Refereed Research - C1)
Keywords: electrochemical oxidation; luminescence; absorption; complexes
ISSN: 1477-9234
Date Deposited: 16 Aug 2012 00:39
FoR Codes: 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 100%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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