Synthesis and properties of mononuclear tris(heteroleptic) osmium(II) complexes containing bidentate polypyridyl ligands

Jandrasics, Erik Z., and Keene, F. Richard (1997) Synthesis and properties of mononuclear tris(heteroleptic) osmium(II) complexes containing bidentate polypyridyl ligands. Dalton Transactions (2). pp. 153-159.

[img] PDF (Published Version) - Published Version
Restricted to Repository staff only

View at Publisher Website: http://dx.doi.org/10.1039/a605161h

Abstract

A general synthetic methodology has been elaborated for tris(bidentate ligand)osmium(II) complexes containing three different polypyridyl ligands. The tris(heteroleptic) complexes were characterized by NMR techniques, and the ligand dependence of their electrochemistry and electronic spectroscopy examined.

Item ID: 22775
Item Type: Article (Refereed Research - C1)
Keywords: transfer excited-states; electronic-spectrum; carbonyl-complexes; redox; potentials; energy-gap; ruthenium(II); factorization ;parameters
ISSN: 1477-9234
Date Deposited: 10 Aug 2012 00:11
FoR Codes: 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 100%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
Downloads: Total: 1
Last 12 Months: 1
More Statistics

Actions (Repository Staff Only)

Item Control Page Item Control Page