From conventional to microphotochemistry: photodecarboxylation reactions involving phthalimides

Shvydkiv, Oksana, Gallagher, Sonia, Nolan, Kieran, and Oelgemöller, Michael (2010) From conventional to microphotochemistry: photodecarboxylation reactions involving phthalimides. Organic Letters, 12 (22). pp. 5170-5173.

[img] PDF (Published Version) - Published Version
Restricted to Repository staff only

View at Publisher Website: http://dx.doi.org/10.1021/ol102184u

Abstract

A series of acetone-sensitized photodecarboxylation reactions involving phthalimides have been investigated using conventional and microphotochemistry. Both, intra- and intermolecular transformations were compared. In all cases examined, the reactions performed in microreactors were superior in terms of conversions or isolated yields. These findings unambiguously prove the advantage of microphotochemistry over conventional photochemical techniques.

Item ID: 16786
Item Type: Article (Refereed Research - C1)
ISSN: 1523-7052
Date Deposited: 10 May 2011 11:43
FoR Codes: 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 50%
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030504 Organic Green Chemistry @ 20%
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 30%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
Citation Count from Web of Science Web of Science 25
Downloads: Total: 2
More Statistics

Actions (Repository Staff Only)

Item Control Page Item Control Page