Photosensitized addition of isopropanol to furanones in a continuous-flow dual capillary microreactor
Yavorskyy, Alexander, Shvydkiv, Oksana, Nolan, Kieran, Hoffmann, Norbert, and Oelgemöller, Michael (2011) Photosensitized addition of isopropanol to furanones in a continuous-flow dual capillary microreactor. Tetrahedron Letters , 52 (2). pp. 278-280.
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Abstract
A novel continuous-flow photoreactor with parallel capillaries was constructed and successfully tested for the DMBP-sensitized addition of isopropanol to furanones. Complete conversions were achieved after a maximum of 10 min of irradiation with a single 350 nm lamp. The results were compared to analogous batch experiments using a conventional Rayonet chamber reactor equipped with 16 UVA lamps. The capillary tower generally showed higher space-time yields.
| Item ID: | 16783 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1873-3581 |
| Keywords: | photoaddition; furanones; photochemistry; microreactor; microcapillary; continuous-flow synthesis |
| Date Deposited: | 16 Jun 2011 00:46 |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 40% 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 40% 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030504 Organic Green Chemistry @ 20% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
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