Dimeric Structure of [(n2-NO3)2(tpy)Bi(μ-OH)2Bi(tpy)(n2-NO3)2]

Junk, Peter C., and Louis, Lance M. (2000) Dimeric Structure of [(n2-NO3)2(tpy)Bi(μ-OH)2Bi(tpy)(n2-NO3)2]. Zeitschrift für Anorganische und Allgemeine Chemie, 626 (2). pp. 556-559.

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Abstract

The synthesis and single crystal X-ray structure determination are reported for the 2,2' : 6',2"-terpyridine (= tpy) adduct of bismuth(III) nitrate. The hydroxide-bridged dimer [(η²-NO₃)₂(tpy)Bi(μ-OH)₂Bi(tpy)(η²-NO₃)₂] with nine-coordinate geometry about Bi was the only isolable product from all crystallization attempts in varying ratios of Bi(NO3) : terpy.; [(η²-NO₃)₂(tpy)Bi(μ-OH)₂Bi(tpy) · (η²-NO₃)₂] is triclinic, P 1, a = 7.941(8), b = 10.732(9), c = 11.235(9)Å; α = 63.05(1), β = 85.01(1), γ = 79.26(1)°, Z = 1, dimer, R = 0.058 for N0 = 2319.

Item ID: 13056
Item Type: Article (Refereed Research - C1)
ISSN: 1521-1749
Date Deposited: 16 Jul 2012 03:22
FoR Codes: 03 CHEMICAL SCIENCES > 0306 Physical Chemistry (incl Structural) > 030606 Structural Chemistry and Spectroscopy @ 51%
03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030204 Main Group Metal Chemistry @ 49%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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